dc.contributor.author | Demir, Selçuk | |
dc.contributor.author | Çepni, Hamide Merve | |
dc.contributor.author | Bilgin, Nuray | |
dc.contributor.author | Holynska, Malgorzata | |
dc.contributor.author | Yılmaz, Fatih | |
dc.date.accessioned | 2020-12-19T19:50:17Z | |
dc.date.available | 2020-12-19T19:50:17Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Demir, S., Cepni, H.M., Bilgin, N., Holynska, M., Yilmaz, F. (2016). Metal-organic frameworks based on copper(I) iodide and pyridine-3,5-dicarboxylic acid: Synthesis, crystal structures and luminescent properties. Polyhedron, 115, 236-241. https://doi.org/10.1016/j.poly.2016.05.008 | en_US |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | https://doi.org/10.1016/j.poly.2016.05.008 | |
dc.identifier.uri | https://hdl.handle.net/11436/2408 | |
dc.description | YILMAZ, Fatih/0000-0002-7711-0975; Demir, Selcuk/0000-0002-5719-7145 | en_US |
dc.description | WOS: 000382349000029 | en_US |
dc.description.abstract | Two metal -organic frameworks (MOFs) with pyridine-3,5-dicarboxylic acid (H(2)pdc), {[(CuI)-I-I][Cu-II(pdc) (H2O)]center dot 1.5MeCN center dot H2O} (1) and {[Cu(MeCN)(4)]center dot 2[(CuI)-I-I]center dot 2[Cu(2)(II)pdc)(2)(H2O)(1.5)(OH)(0.5)]center dot MeCN4AcOH-8H(2)O}(n), (2) (MeCN = acetonitrile, AcOH = acetic acid), containing both [CuxIx] (x = 4 for 1 and x = 2 for 2) and Cu-2(COO)(4) clusters at the same time, were synthesized solvothermally and characterized by means of spectroscopic and X-ray diffraction techniques. These MOFs are constructed of Cu+/Cu2+ cations, pyridine-3,5-dicarboxylate and iodide anions and water molecules as terminal ligands. [Cu(MeCN)(4)](+) complex cations are embedded in the channels of 7.7 x 9.2 angstrom diameter in between the columns of the [Cu2I2] units of the compound 2. the Brauner-Emmett-Teller specific surface areas are of 498 and 515 m(2)/g for 1 and 2, respectively. While 1 and 2 show cluster-based luminescence, the luminescent property of 2 is "on" after 2-nitro toluene loading. (C) 2016 Elsevier Ltd. All rights reserved. | en_US |
dc.description.sponsorship | The Scientific and Technological Research Council of Turkey, (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [112T956] | en_US |
dc.description.sponsorship | The authors gratefully acknowledge funding from the Scientific and Technological Research Council of Turkey, (TUBITAK) under Project Number 112T956. M.H. thanks to Prof. Dr. Stefanie Dehnen and to Prof. Dr. Florian Kraus (generous support), as well as to Michael Marsch (support with X-ray diffraction studies). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Metal-organic framework | en_US |
dc.subject | Pyridine-3,5-dicarboxylic acid | en_US |
dc.subject | Porosity | en_US |
dc.subject | Luminescent | en_US |
dc.subject | Cluster | en_US |
dc.title | Metal-organic frameworks based on copper(I) iodide and pyridine-3,5-dicarboxylic acid: Synthesis, crystal structures and luminescent properties | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Demir, Selçuk | |
dc.contributor.institutionauthor | Çepni, Hamide Merve | |
dc.contributor.institutionauthor | Bilgin, Nuray | |
dc.contributor.institutionauthor | Yılmaz, Fatih | |
dc.identifier.doi | 10.1016/j.poly.2016.05.008 | |
dc.identifier.volume | 115 | en_US |
dc.identifier.startpage | 236 | en_US |
dc.identifier.endpage | 241 | en_US |
dc.relation.journal | Polyhedron | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |