Microwave-assisted synthesis, characterization and spectral properties of non-peripherally tetra-substituted phthalocyanines containing eugenol moieties
Künye
Kantar, C., Sahin, Z.S., Buyukgungor, O., Sasmaz, S. (2015). Microwave-assisted synthesis, characterization and spectral properties of non-peripherally tetra-substituted phthalocyanines containing eugenol moieties. Journal of Molecular Structure, 1089, 48-52. https://doi.org/10.1016/j.molstruc.2015.02.044Özet
The microwave-assisted synthesis and characterization of novel non-peripherally eugenol substituted metallophthalocyanines (M: Co(II), Ni(II), Cu(II), Zn(II)) have been reported for the first time in this study. All the new compounds were characterized by a combination of FT-IR, H-1 NMR, C-13 NMR, and UV/vis spectroscopy techniques. the crystal structure of compound (1) was also determined by the single crystal diffraction technique. Newly synthesized eugenol substituted phthalocyanines have more redshift Q bands (about 17-18 nm) than previously reported eugenol substituted phthalocyanines. Zinc(II)phthalocyanine (1d) has an extra absorption band at 746 nm that calling "X band" at UV/vis spectrum. (C) 2015 Elsevier B.V. All rights reserved.
