Synthesis, characterization and properties of tetra((l-hydroxyimino- methylnaphthalen-2-yloxy)methyl)etheneandits homo-dinuclear metal complexes: A combined experimental and theoretical investigation

Abstract

Tetra((l-hydroxyiminomethylnaphthalen-2-yloxy)methyl)ethene (THlMNYOME), H4L, was synthesized by the agents of 2-hydroxy-l -naphtaldehyde, tetra(bromomethyl)ethene and hydroxylamine hydrochloride in two steps. Characterization of THIMNYOME and its dinuclear complexes was made by elemental analyses, IR, 1H- and 13C NMR, UV-vis, electrospray ionisation mass spectra, molar conductivities and magnetic susceptibility measurements. In the light of these results, it was suggested that the ligand coordinate to each metal atom by the two ether oxygen, two nitrogen atoms of oxime (C-N) and an axial oxygen of Perchlorate to form pseudo square-pyramidal complexes with Ni(II), Cu(Il) and Zn(II). Molar conductivity measurements reveal that all the complexes are non-electrolytes. In addition, the full geometric optimization of the tetraoxime ligand (4) has been made by the B3LYP/6-31G(d) level in order to establish a stable conformation. Additionally, all the complex structures have been studied in the B3LYP/LANL2DZ level. NBO charge distribution and the characteristics of frontier molecular orbitais of these complexes have also been investigated in order to see the electrons movement between ligand and metal atom in the same level. © 2010 Elsevier B.V. All rights reserved.