dc.contributor.author | Soyer, Eda | |
dc.contributor.author | Yılmaz, Fatih | |
dc.contributor.author | Yılmaz, Veysel T. | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.contributor.author | Harrison, William T.A | |
dc.date.accessioned | 2020-12-19T20:11:41Z | |
dc.date.available | 2020-12-19T20:11:41Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Soyer, E., Yılmaz, F., Yılmaz, V.t., Büyükgüngör, O. & Harrison, W.T.A. (2010). Synthesis, characterization, crystal structures and thermal and fluorescence studies of dinuclear and polymeric silver(I) complexes of 5,5-diethylbarbiturate with 2,5-dimethylpyrazine and piperazine involving Ag-Ag interactions. Journal of Inorganic and Organometallic Polymers and Materials, 20(2), 320-325. https://doi.org/10.1007/s10904-010-9342-0 | en_US |
dc.identifier.issn | 1574-1443 | |
dc.identifier.uri | https://doi.org/10.1007/s10904-010-9342-0 | |
dc.identifier.uri | https://hdl.handle.net/11436/3769 | |
dc.description.abstract | Two silver(I) complexes, [Ag(dmpyz) 2][Ag(barb) 2] (1) and {[Ag(ppz)][Ag(barb) 2]·H 2O} n (2) (barb = 5,5-diethylbarbiturate, dmpyz = 2,5-dimethylpyrazine and ppz = piperazine), have been synthesized and characterized by elemental analyses, IR, thermal analysis (TG-DTA) and single-crystal X-ray diffraction. Complex 1 consists of [Ag(dmpyz) 2] + and [Ag(barb) 2] - ions in which the silver(I) ions are linearly coordinated by two dmpyz or two barb ligands. These two ions are connected by strong Ag-Ag interactions (Ag-Ag = 2.896 (1) Å). Complex 2 is a 1D coordination polymer in which the silver(I) ions are bridged by the ppz ligands in a linear fashion, leading to a zigzag chain of [Ag(ppz)] n +, which interacts with the [Ag(barb) 2] - units by Ag-Ag interactions of 3.183 (1) Å. The 1D chains are further assembled to form 3D networks by strong N-H···O and OW-H···O hydrogen bonds. IR spectra and TG-DTA data are in agreement with the crystal structures. The fluorescent properties of 1 were also evaluated. © 2010 Springer Science+Business Media, LLC. | en_US |
dc.description.sponsorship | F-2008/56 | en_US |
dc.description.sponsorship | Acknowledgments We thank the research fund of Uludag University for the financial support given to the research project (F-2008/56). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Springer Link | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 2,5-Dimethylpyrazine | en_US |
dc.subject | 5,5-Diethylbarbiturate | en_US |
dc.subject | Ag-Ag interactions | en_US |
dc.subject | Coordination polymer | en_US |
dc.subject | Piperazine | en_US |
dc.title | Synthesis, characterization, crystal structures and thermal and fluorescence studies of dinuclear and polymeric silver(I) complexes of 5,5-diethylbarbiturate with 2,5-dimethylpyrazine and piperazine involving Ag-Ag interactions | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Yılmaz, Fatih | |
dc.identifier.doi | 10.1007/s10904-010-9342-0 | |
dc.identifier.volume | 20 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.startpage | 320 | en_US |
dc.identifier.endpage | 325 | en_US |
dc.relation.journal | Journal of Inorganic and Organometallic Polymers and Materials | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |