Güncel Gönderiler: FEF, Kimya Bölümü Koleksiyonu
Toplam kayıt 481, listelenen: 181-200
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Experimental and computational studies on 4-[(3,5-dimethyl-1H-pyrazol-1-yl) methoxy]phthalonitrile and synthesis and spectroscopic characterization of its novel phthalocyanine magnesium(ii) and tin(ii) metal complexes
(Elsevier B.V., 2013)The molecular structure of the substituted phthalonitrile was analyzed crystallographically and compared with optimized geometric structure. The structural properties of the compound such as energy, vibrational frequency, ... -
Rapid and efficient microwave-assisted synthesis of some new triazol-3-one derivatives
(Wiley, 2013)A growing body of literature has shown the effectiveness of using microwaves in chemical reactions. The aim of this study is to demonstrate a rapid and highly efficient synthesis of some new triazol-3-ones via microwave ... -
Microwave-assisted synthesis of some 1, 2, 4-triazol-3-ones and potentiometric determination of their pKa in amfiprotic and dipolar aprotic-water mixtures
(0-Belirlenecek, 2013)The novel 5-alkyl(aryl)-4-(aryl)-2, 4-dihydro-3H-1, 2, 4-triazol-3-ones (1-12) were synthesized by reaction of (N?-ethoxycarbonyl)-4-alkyl(aryl)hydrazonic acid ethyl ester with primary amines by microwave irradiation. ... -
Efficient synthesis of 5-(substituted)benzyl-2,4-dihydro-3H-1,2,4-triazol- 3-ones using microwave irradiation
(2013)A growing body of literature has shown the effectiveness of using microwave irradiation in chemical reactions. The aim of this study is to demonstrate a rapid and highly efficient synthesis of some new 5-aryl-2,4-dihydro-3H-1,2,4- ... -
Synthesis and in vitro antioxidant activities of novel 4-(3-methyl-2- thienylmethyleneamino)-4,5-dihydro-1H-1,2,4-triazol-5-one derivatives with their acidic properties
(2013)In the present study 3-alkyl(aryl)-4-amino-4,5-dihydro-1H-1,2,4-triazol-5- ones 2a-i reacted with 3-methyl-thiophene-2-carboxyaldehyde to afford the corresponding 3-alkyl(aryl)-4-(3- methyl-2-thienylmethyleneamino)-4,5-dihydro- ... -
Characterization of unye bentonite after treatment with sulfuric acid
(SOC Brasileira Quimica, 2013)Unye bentonite was found to consist predominantly of a dioctahedral smectite along with quartz, tridymite, cristobalite, and minor fractions of feldspar and anatase. A considerable amount of Al was retained as a constituent ... -
Chemical composition and antimicrobial activity of essential oils from tortella inclinata var. Densa, T. Tortusa and pleurochaete squarrosa
(Chemical Publishing Co., 2014)Although some chemical compositional data are available about the extracts of Tortella tortusa and Pleurochaete squarrosa, there is no investigation about the compositions and antimicrobial activities of the volatiles from ... -
Essential oil analysis and antimicrobial activity of neckera complanata (Hedw.) huebener and neckera crispa Hedw. (Neckeraceae) grown in Turkey
(Chemical Publishing Co., 2014)In this work, the essential oils obtained by hydrodistillation from Neckera complanata (Hedw.) Huebener and Neckera crispa Hedw (Neckeraceae) were analyzed by GC-FID and GC-MS. Twenty-one compounds in the oil of N. complanata, ... -
4-Methyl-N-(4-methylphenylsulfonyl)-N-phenylbenzenesulfonamide
(Int Union Crystallography, 2014)The whole molecule of the title compound, C20H 19NO4S2, is generated by twofold rotational symmetry. The N atom is located on the twofold rotation axis and has a trigonal-planar geometry. It is bonded by two S atoms of two ... -
Evaluation of phenolic compounds in Tilia rubra Subsp. caucasica by HPLC-UV and HPLC-UV-MS/MS
(Taylor & Francis Ltd., 2014)Profile of phenolic compounds of Tilia rubra subsp. caucasica was measured by high performance liquid chromatography coupled with ultraviolet and tandem mass spectroscopy. Three different extraction methods (methonolic, ... -
N-H?N and C-H?? interactions in 4-amino-3-methyl-5-(p- tolyl)-4H-1,2,4-triazole and 4-amino-3-methyl-5-phenyl-4H-1,2,4-triazole
(2006)The title compounds, C10H12N4, (I), and C9H10N4, (II), have been synthesized and characterized both spectroscopically and structurally. The dihedral angles between the triazole and benzene ring planes are 26.59 (9) and ... -
Synthesis and properties of triazol-5-one substituted phthalocyanines by microwave irradiation
(TÜBİTAK, 2006)Triazol-5-one substituted phthalocyanines were prepared quickly by the reaction of 4-nitrophthalonitrile with anhydrous metal salts in DBU (1,8-diazabicyclo[5,4,0]undec-7-ene) and DMAE (dimethylaminoethanol) by microwave ... -
Structural characteristics of organo-modified bentonites of different origin
(Springer, 2007)Organobentonites were synthesized by treating Na-bentonites (Wyoming and Reşadiye) with cetylpyridinium chloride (CPC) using ion exchange method. The difference in the basal spacing by 0.65 Å and a higher mass loss by ... -
2'-[Eth-oxy(p-tol-yl)methyl-ene]acetohydrazide
(2007)Mol-ecules of the title compound, C12H16N2O2, are linked by N - H?O hydrogen bonds [N?O = 2.971 (2) Å, H?O = 2.17 (2) Å and N - H?O = 162 (2)°] into cyclic centrosymmetric R 2 2(8) dimers. © International Union of ... -
2'-[Eth-oxy(phen-yl)methyl-ene]acetohydrazide
(2007)The title compound, C11H14N2O2, contains two independent mol-ecules in the asymmetric unit. Each independent mol-ecule exists as part of an N - H?O hydrogen-bonded centrosymmetric dimer. © International Union of Crystallography ... -
Microwave-assisted synthesis and characterization of novel metal-free and metallophthalocyanines containing four 14-membered tetraaza macrocycles
(Elsevier, 2007)The novel tetrasubstituted metal-free phthalocyanine (6) and metallophthalocyanines (7, 8) bearing four 14-membered tetraaza macrocycles moieties on peripheral positions have been synthesized by cyclotetramerization reaction ... -
Determination of the protonation constants of some 4-(substituted benzylamino)-4,5-dihydro-1H-1,2,4-triazol-5-ones by the potentiometric method in ethanol-water mixtures
(2007)To gain more information about the effect of solvent on 4,5-dihydro-1H-1,2,4-triazol-5-ones, the stoichiometric protonation constants of thirteen triazoles in ethanol-water mixtures were determined at an ionic strength of ... -
4-Amino-3,5-diethyl-4H-1,2,4-triazole at 100 K: Chains of edge-fused R 44(10) and R44(20) rings
(Wiley, 2007)The title compound, C6H12N4, has four crystallographically independent mol-ecules in the asymmetric unit. Inter-molecular N - H?N hydrogen bonds involving amino groups and triazole N atoms form a three-dimensional framework ... -
Newly synthesized bentonite-histidine (Bent-His) micro-composite affinity sorbents for IgG adsorption
(Elsevier, 2007)Bentonite has several advantages for use as a support, including its lack of toxicity, chemical reactivity and hydrophilicity allowing easy fixation of biomolecules. A new approach was developed to obtain an efficient and ... -
A study on 4-acylamino-4,5-dihydro-1H-1,2,4-triazol-5-ones
(2007)Five novel 3-alkyl-4-phenylacetylamino-4,5-dihydro-1H-1,2,4-triazol-5-ones (2) were synthesized by the reactions of 3-alkyl-4-amino-4,5-dihydro-1H-1,2,4- triazol-5-ones (1) with phenylacetyl chloride and characterized by ...
