Güncel Gönderiler: FEF, Kimya Bölümü Koleksiyonu
Toplam kayıt 455, listelenen: 181-200
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The microwave-assisted synthesis and characterization of novel polymeric phthalocyanines containing resorcinarene
(Elsevier, 2008)Novel metal phthalocyanine (Cu, Zn, Co, Ni) polymers containing resorcinarene moieties were prepared; the resorcinarene was obtained by the acid-catalysed cyclocondensation of resorcinol and acetaldehyde under microwave ... -
Synthesis and crystal structure of N-(3-methyl-5-phenyl-3,5-dihydro-4H-1,2,4-triazol-4-yl)benzamide
(Japan Society for Analytical Chemistry, 2008)The title compound, N-(3-methyl-5-phenyl-3,5-dihydro-4H-1,2,4-triazol-4-yl)benzamide, C16H14N4O, crystallizes in the monoclinic space group P21/c with the following unit cell parameters: a = 10.6011(6)Å, b = 7.5676(4)Å, c ... -
Synthesis and anticancer evaluation of some new 4-amino-3-(p-methoxybenzyl) -4,5-dihydro-1,2,4-triazole-5-one derivatives
(Verlag der Zeitschrift fur Naturforschung, 2008)4-Amino-3-p-methoxybenzyl-5-oxo-4,5-dihydro-1,2,4-triazol-1-yl-acetic acid ethyl ester (2) was prepared from 4-amino-4,5-dihydro-1H-1,2,4-triazole-5-one (1) and ethyl bromoacetate. Compound 3 was synthesized by the ... -
Studies on the protonation constants of some triazoles in ethanol-water mixtures
(Chemical Publishing Co., 2008)Several studies, involving the formation and investigation of biological activities of some triazoles derivatives. These derivatives have weak acidic properties. To gain more information about the effect of solvent on ... -
Reversible immobilization of catalase by using a novel bentonite-cysteine (Bent-Cys) microcomposite affinity sorbents
(Elsevier, 2008)This study focused on developing bentonite-cysteine (Bent-Cys) microcomposite affinity sorbents (38-105 ?m) for catalase adsorption from aqueous solutions. Pseudo-biospecific affinity ligand l-cysteine was covalently binded ... -
Binuclear transition metal complexes of a novel lateral ‒N-methylthiosemicarbazone through the central ethylene bridge: Synthesis, structural characterization and the response of ligand molecule to different solvent media
(Elsevier, 2008)The condensation of 2,2?-(2,3-bis((1-formylnaphthalen-2-yloxy)methyl)but-2-ene-1,4-diy l)bis(oxy)di-1-naphthaldehyde with 4-methyl thiosemicarbazide gave a novel N-methylthiosemicarbazone and then the reaction of this ... -
Synthesis, potentiometric titrations and antioxidant activities of some 4-acylamino-4,5-dihydro-1H-1,2,4-triazol-5-one derivatives
(2008)Five novel 3-alkyl-4-cinnamoylamino-4,5-dihydro-1H-1,2,4-triazol-5-ones (2) were synthesized by the reactions of 3-alkyl-4-amino-4,5-dihydro-1H-1,2,4- triazol-5-ones (1) with cinnamoyl chloride and characterized by elemental ... -
Ni(II), Cu(II), and Zn(II) complexes of tetradentate schiff base containing two thiadiazoles units: Structural, spectroscopic, magnetic properties, and molecular modeling studies
(Wiley, 2008)Four new mononuclear metal complexes with a mononucleating Schiff base ligand containing two thiadiazoles units have been synthesized. The ligand and metal complexes were characterized by elemental analyses, IR, 1H, and ... -
Microwave-assisted synthesis and antifungal activity of some new 1H-1,2,4-triazole derivatives
(Springer, 2008)A number of 3-aryl-4-arylmethylideneamino-4,5-dihydro-1H-1,2,4-triazol-5- ones were synthesized by reaction of the corresponding aromatic aldehydes with 4-amino-3-aryl-1H-1,2,4-triazol-5-ones in anhydrous ethanol under ... -
Structural analysis of reactive dye species retained by the basic alumina surface
(Springer, 2009)The alumina-dye composites were prepared by treating the basic alumina with the water solutions of Reactive Red 120 (RR 120) and Reactive Blue 15 (RB 15) dyes. The bands of low intensities in the 1400-1600 cm-1 region and ... -
Determination of adsorptive properties of a Turkish Sepiolite for removal of Reactive Blue 15 anionic dye from aqueous solutions
(Elsevier, 2009)Reactive Blue 15 (RB 15) adsorption on the Turkish Sepiolite was carried out by batch equilibrium technique. IR spectrum and surface area measurement of the composite of dye-sepiolite (Turkish) pointed out that dye species ... -
Determination of the protonation constants of triazole derivatives in non-aqueous solvents
(2009)Different 17 triazole derivatives were titrated with tetrabutylammonium hydroxide in four non-aqueous solvents (isopropyl alcohol, rert-butyl alcohol, N,N-dimethylformamide and acetonitrile), using Potentiometric method. ... -
Synthesis of 1,2,4-Triazole derivatives and determination of protonation constant
(2009)A microwave irradiation method has been developed for the synhesis of some 1,2,4-triazole derivatives using environmentally benign solvent ethanol in open vessels. Twelve 1,2,4-triazole derivatives were synthesized in good ... -
Synthesis of methyl (E)-2′,4″-thiazachalcones and their N-alkyl derivatives, photochemistry with theoretical calculations and antimicrobial activities
(TUBİTAK, 2009)A series of 9 new (E) -thiazachalcones (1-3), and their N -alkyl substituted derivatives (4-6), and stereoselective dimerization products (7-9) were synthesized, then tested for antimicrobial activity against all test ... -
The microwave-assisted synthesis and characterization of novel, octakis(2-hydroxyethoxy)resorcinarene bridged polymeric metallophthalocyanines
(Elsevier, 2009)The new metallophthalocyanine (Zn, Cu, Ni, Co) polymers containing 4,6,10,12,16,18,22,24-octakis(2-hydroxyethoxy)-2,8,14,20-tetramethylresorcinarene are described. Firstly, 4,6,10,12,16,18,22,24-octakis(2-hydroxyethoxy)- ... -
3-Ethyl-4-(p-chlorobenzylidenamino-4,5-dihydro-1H-1,2,4-triazol-5-one (EPHBAT) as precipitant for carrier element free coprecipitation and speciation of chromium(III) and chromium(VI)
(Elsevier, 2009)A method for the separation and speciative determination of Cr(VI) and Cr(III) has been developed. The procedure is based on coprecipitation of Cr(III) on 3-ethyl-4-(p-chlorobenzylidenamino-4,5-dihydro-1H-1,2,4-triazol-5-one ... -
Novel phthalocyanines containing substituted salicyclic hydrazone-1,3-thiazole moieties: Microwave-assisted synthesis, spectroscopic characterization, X-ray structure and thermal characterization
(Elsevier, 2010)Novel, metal-free and metallo(Cu, Co, Ni, Zn, Pb and Mn)phthalocyanine compounds were synthesized by exposure to microwave irradiation and the products purified. The newly prepared compounds were characterized using elemental ... -
The spectral, structral and thermal characterizations of dimethyl sulphoxide, pyridine, ethanolamine and N-methyl formamide intercalated kaolinites
(Verlag der Zeitschrift fur Naturforschung, 2010)The intercalation of dimethyl sulphoxide (DMSO), pyridine (Py), ethanolamine (Ea), and Nmethyl formamide (NMF) molecules into the kaolinite interlayers led to an appreciable decrease of 3697 cm-1 of the hydroxyl band. The ... -
Purification and characterisation of a polyphenol oxidase from Boletus erythropus and investigation of its catalytic efficiency in selected organic solvents
(Elsevier, 2010)Polyphenol oxidase (PPO) was purified from Boletus erythropus using a Sepharose 4B-L-tyrosine-p-amino benzoic acid affinity column. Optimum pH and temperature were found to be 8.0 and 20 °C, respectively, using 4-methylcatechol ... -
Metal(II) nicotinamide complexes containing succinato, succinate and succinic acid: Synthesis, crystal structures, magnetic, thermal, antimicrobial and fluorescent properties
(Springer Link, 2010)Four novel divalent transitional metal succinates (suc) with nicotinamide (nia), {[M(?-suc)(H 2O) 2(nia) 2]·2H 2O} n [M = Mn (1), Ni (2)], [Cu(suc)(nia) 2] (3) and [Ni(H 2O) 4(nia) 2](suc)·(H 2suc) (4), have been synthesized ...