Güncel Gönderiler: FEF, Kimya Bölümü Koleksiyonu
Toplam kayıt 481, listelenen: 221-240
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The microwave-assisted synthesis and characterization of novel, octakis(2-hydroxyethoxy)resorcinarene bridged polymeric metallophthalocyanines
(Elsevier, 2009)The new metallophthalocyanine (Zn, Cu, Ni, Co) polymers containing 4,6,10,12,16,18,22,24-octakis(2-hydroxyethoxy)-2,8,14,20-tetramethylresorcinarene are described. Firstly, 4,6,10,12,16,18,22,24-octakis(2-hydroxyethoxy)- ... -
3-Ethyl-4-(p-chlorobenzylidenamino-4,5-dihydro-1H-1,2,4-triazol-5-one (EPHBAT) as precipitant for carrier element free coprecipitation and speciation of chromium(III) and chromium(VI)
(Elsevier, 2009)A method for the separation and speciative determination of Cr(VI) and Cr(III) has been developed. The procedure is based on coprecipitation of Cr(III) on 3-ethyl-4-(p-chlorobenzylidenamino-4,5-dihydro-1H-1,2,4-triazol-5-one ... -
Novel phthalocyanines containing substituted salicyclic hydrazone-1,3-thiazole moieties: Microwave-assisted synthesis, spectroscopic characterization, X-ray structure and thermal characterization
(Elsevier, 2010)Novel, metal-free and metallo(Cu, Co, Ni, Zn, Pb and Mn)phthalocyanine compounds were synthesized by exposure to microwave irradiation and the products purified. The newly prepared compounds were characterized using elemental ... -
The spectral, structral and thermal characterizations of dimethyl sulphoxide, pyridine, ethanolamine and N-methyl formamide intercalated kaolinites
(Verlag der Zeitschrift fur Naturforschung, 2010)The intercalation of dimethyl sulphoxide (DMSO), pyridine (Py), ethanolamine (Ea), and Nmethyl formamide (NMF) molecules into the kaolinite interlayers led to an appreciable decrease of 3697 cm-1 of the hydroxyl band. The ... -
Purification and characterisation of a polyphenol oxidase from Boletus erythropus and investigation of its catalytic efficiency in selected organic solvents
(Elsevier, 2010)Polyphenol oxidase (PPO) was purified from Boletus erythropus using a Sepharose 4B-L-tyrosine-p-amino benzoic acid affinity column. Optimum pH and temperature were found to be 8.0 and 20 °C, respectively, using 4-methylcatechol ... -
Metal(II) nicotinamide complexes containing succinato, succinate and succinic acid: Synthesis, crystal structures, magnetic, thermal, antimicrobial and fluorescent properties
(Springer Link, 2010)Four novel divalent transitional metal succinates (suc) with nicotinamide (nia), {[M(?-suc)(H 2O) 2(nia) 2]·2H 2O} n [M = Mn (1), Ni (2)], [Cu(suc)(nia) 2] (3) and [Ni(H 2O) 4(nia) 2](suc)·(H 2suc) (4), have been synthesized ... -
Synthesis, characterization, crystal structures and thermal and fluorescence studies of dinuclear and polymeric silver(I) complexes of 5,5-diethylbarbiturate with 2,5-dimethylpyrazine and piperazine involving Ag-Ag interactions
(Springer Link, 2010)Two silver(I) complexes, [Ag(dmpyz) 2][Ag(barb) 2] (1) and {[Ag(ppz)][Ag(barb) 2]·H 2O} n (2) (barb = 5,5-diethylbarbiturate, dmpyz = 2,5-dimethylpyrazine and ppz = piperazine), have been synthesized and characterized by ... -
Equilibrium and kinetic studies on the removal of basic dye using raw and thermal-activated fatsa bentonite
(2010)The adsorption behavior of crystal violet (CV+) from aqueous solution onto raw Fatsa (RFB) and thermalactivated Fatsa (TAFB) bentonite samples was investigated as a function of parameters, such as pH, temperature, initial ... -
Cloning, expression and characterization of highly thermo- and pH-stable maltogenic amylase from a thermophilic bacterium Geobacillus caldoxylosilyticus TK4
(Elsevier, 2010)Maltogenic amylases (MAases), a subclass of cyclodextrin (CD)-hydrolyzing enzymes, belong to glycoside hydrolase family 13. A gene corresponding to MA in Geobacillus caldoxylosilyticus TK4 (GcaTK4MA) was cloned into pET28a(+) ... -
Performance of magnesium oxide-coated bentonite in removal process of copper ions from aqueous solution
(Elsevier, 2010)This paper presents the adsorption of Cu(II) ions from aqueous solution on modified Unye bentonite. Adsorption of Cu(II) ions by magnesium oxide-coated bentonite (MCB) sample was investigated as a function of the initial ... -
Photodimerizations of hydroxy- and benzoylated 4-azachalcones and quantum chemical investigation of the reactions
(Springer Link, 2010)Photodimerization reactions of compounds 4-6 gave four new cyclobutane-containing compounds (7-9) with full control over the stereochemistry at the four stereogenic centers. These new cyclobutane- containing compounds had ... -
Adsorption of Reactive Red 120 from aqueous solutions by cetylpyridinium-bentonite
(Wiley, 2010)BACKGROUND: The removal of Reactive Red 120 (RR 120) from aqueous solutions using cetylpyridinium modified Resadiye bentonite (CP-bentonite) prepared by ion exchange was investigated with particular reference to the effects ... -
Volatile constituents and antimicrobial activities from flower and fruit of arbutus unedo L.
(2010)Essential oils isolated by hydrodistillation from flower and fruit of Arbutus unedo growing in Turkey were analyzed by GC and GC/MS. Forty-nine compounds, representing around 95% of the total oils were identified. ... -
Radiological and chemical assessment of phosphate rocks in some countries
(Elsevier, 2010)In this study, the radiological, structural and chemical characterizations of Mardin-Mazi{dotless}da?i{dotless} phosphate rock, which is an important phosphate fertilizer source in Turkey were investigated and compared to ... -
Microwave-assisted synthesis of novel 2,4-dihydro-5-[4-(trifluoromethyl) phenyl]-3h-1,2,4-triazol-3-ones and potentiometric determination of their pKa in nonaqueous solvents
(Wiley, 2010)The novel 4-amino- or 4-aryl-substituted 2,4-dihydro-5-[(4-trifluoromethyl) phenyl]-3H-1,2,4-triazol-3-ones 3a-3g were synthesized by reaction of N-(ethoxycarbonyl)-4-(trifluoromethyl)benzenehydrazonic acid ethyl ester (2) ... -
Synthesis, characterization and properties of tetra((l-hydroxyimino- methylnaphthalen-2-yloxy)methyl)etheneandits homo-dinuclear metal complexes: A combined experimental and theoretical investigation
(Elsevier B.V., 2010)Tetra((l-hydroxyiminomethylnaphthalen-2-yloxy)methyl)ethene (THlMNYOME), H4L, was synthesized by the agents of 2-hydroxy-l -naphtaldehyde, tetra(bromomethyl)ethene and hydroxylamine hydrochloride in two steps. Characterization ... -
Syntheses, crystal structures, spectroscopic, fluorescence and thermal properties of silver(I) 5,5-diethylbarbiturato complexes with some aminopyridines
(Elsevier S.A., 2010)Three new silver(I) complexes of 5,5-diethlybarbiturate (barb), [Ag(barb)(apy)]·H2O (1), {[Ag(?-ampy)][Ag(?-barb) 2]}n (2) and [Ag(barb)(dmamhpy)] (3) [apy = 2-aminopyridine, ampy = 2-aminomethylpyridine and dmamhpy = 2- ... -
InVitro antioxidant activities of new 4,5-dihydro-1H-1,2,4-triazol-5-ones having thiophene ring with their acidic properties
(Hindawi, 2011)Seven new 3-alkyl(aryl)-4-(2-thienymethylenamino)-4,5-dihydro- 1H-1,2,4-triazol-5-ones (2) were synthesized by the reactions of 3-alkyl(aryl)- 4-amino-4,5-dihydro-1H-1,2,4-triazol-5-ones (1) with thiophene-2-carbaldehyde. ... -
Syntheses, crystal structures, fluorescent, and thermal properties of nickel(II) 5,5-diethylbarbiturate complexes with (2-aminomethyl), (2-aminoethyl), and (2-hydroxyethyl)pyridines
(Taylor & Francis, 2011)Three nickel(II) complexes of 5,5-diethlybarbiturate (barb) with (2-aminomethyl)pyridine (ampy), (2-aminoethyl)pyridine (aepy), and (2-hydroxyethyl)pyridine (hepy), [Ni(barb-N)2(ampy)2] (1), [Ni(barb-N,O)(aepy)2](barb)·H2O ... -
Structural characterization of aniline-bentonite composite by FTIR, DTA/TG, and PXRD analyses and BET measurement
(Taylor & Francis, 2011)The aniline species incorporated into the acid-activated bentonite matrices leads to the decay of the skeletal stretches centered at 1041 cm-1 and the rise of new features in the phenyl ring frequency region, 1700-1400 ...
